新型荧光光子晶体薄膜及其在染料敏化太阳能电池背反射层中的应用A novel fluorescent photonic film as back-reflecting layers for efficiency enhancement in dye-sensitized solar cells(DSSC)
马晓飞,魏来,朱祥,朱玉华,马鹏常,李金华,王建颖
摘要(Abstract):
通过水热-垂直沉积法制备了一种新型的荧光光子晶体薄膜,得到的荧光光子晶体具有鲜艳的色彩和良好的荧光性能.此薄膜在460 nm处有明显的反射峰,在440 nm处有很强的荧光峰.将此荧光光子晶体薄膜作为染料敏化太阳能电池背反射层时,可以将开路电压由0.75 V提高到0.77 V,短路电流由7.64 m A/cm2提高到8 m A/cm2,光电转换效率由4.13%提高到4.23%,可以提高2.42%的光电转换效率.
关键词(KeyWords): 二氧化硅胶体;碳点;光子晶体;背反射层
基金项目(Foundation): 湖北省教育厅自然科学基金(Q20161010)资助
作者(Author): 马晓飞,魏来,朱祥,朱玉华,马鹏常,李金华,王建颖
参考文献(References):
- [1]Yu Z,Chen L,Chen S.Uniform fluorescent photonic crystal supraballs generated from nanocrystal-loaded hydrogelmicrospheres[J].J Mater Chem,2010,20:6182.
- [2]Achelle S,Blanco A,Sapienza R,et al.New poly(phenylenevinylene)‐methyl methacrylate‐based photonic crystals[J].J Polym Sci Part A:Polym Chem,2010,48(12):2659.
- [3]Galisteo-López J,Ibisate M,Mu1oz A,et al.3D photonic crystals from highly monodisperse FRET-based red luminescent PMMA spheres[J].J Mater Chem C,2015,3(16):3999.
- [4]Hu Y,Wang J,Wang H,et al.Microfluidic fabrication and thermoreversible response of core/shell photonic crystalline microspheres based on deformable nanogels[J].Langmuir,2012,28(49):17186.
- [5]Klimonsky S,Knotko A,Borodinov N,et al.Control over the distribution of luminescent impurities inside opal photonic crystals[J].Superlattices and Microstructures,2015,85:615.
- [6]Kolaric B,Baert K,Van Der Auweraer M,et al.Controlling the fluorescence resonant energy transfer by photonic crystal band gap engineering[J].Chem Mater,2007,19(23):5547.
- [7]Liu K,Tsu R.Photoluminescence enhancement of quantum dots with photonic structures[J].Microelectronics Journal,2009,40(4):741.
- [8]Yan L,Yu Z,Chen L,et al.Controllable fabrication of nanocrystal-loaded photonic crystals with a polymerizable macromonomer via the CCTP technique[J].Langmuir,2010,26(13):10657.
- [9]Zhang Y Q,Wang J X,Ji Z Y,et al.Solid-state fluorescence enhancement of organic dyes by photonic crystals[J].J Mater Chem,2007,17(1):90.
- [10]Zou L,Sui N,Wang Y-H,et al.Fluorescence resonance energy transfer between conjugated molecules infiltrated in threedimensional opal photonic crystals[J].J Lumin,2015,158:281.
- [11]Li H,Xu Z.Photoluminescence manipulation based on composite photonic crystal surfaces[J].J Lumin,2013,143:288.
- [12]Tang B,Zhao X,Zhao Y,et al.Binary optical encoding strategy for multiplex assay[J].Langmuir,2011,27(18):11722.
- [13]Capek R K,Weber M,EychmüLler A.Alternative incorporation procedure of quantum dots in polymer microspheres[J].Chem Mater,2010,22(17):4912.
- [14]Dechézelles J-F,Aubert T,Grasset F,et al.Fine tuning of emission through the engineering of colloidal crystals[J].Physical Chemistry Chemical Physics,2010,12(38):11993.
- [15]Diacon A,Rusen E,Mocanu A,et al.Fluorescence properties of photonic crystals doped with perylenediimide[J].Langmuir,2011,27(12):7464.
- [16]Fleischhaker F,Zentel R.Photonic crystals from core-shell colloids with incorporated highly fluorescent quantum dots[J].Chem Mater,2005,17(6):1346.
- [17]Lawrence J R,Shim G H,Jiang P,et al.Dynamic tuning of photoluminescent dyes in crystalline colloidal arrays[J].Adv Mater,2005,17(19):2344.
- [18]Zhang J,Ling L,Wang C F,et al.Versatile dendrimer-derived nanocrystal microreactors towards fluorescence colloidal photonic crystals[J].J Mater Chem C,2014,2(18):3610.
- [19]戴广超,魏来,马晓飞,等.荧光光子晶体背反射层增强染料敏化太阳能电池效率[J].湖北大学学报(自然科学版),2017,39(4):343.
- [20]St9ber W,Fink A,Bohn E.Controlled growth of monodisperse silica spheres in the micron size range[J].Journal of Colloid&Interface Science,1968,26(1):62.